| A-H键振动频率与原子价层轨道能 |
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| 引用本文： | 喻典.A-H键振动频率与原子价层轨道能[J].湖北师范学院学报(哲学社会科学版),1992(6). |
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| 作者姓名： | 喻典 |
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| 摘 要： | 本文研究了原子价层轨道能与共价型分子氢化物中A-H键的振动频率v_(A-H)的关系,结果表明二者间有良好的线性关系,其计算式为: v_(A-H)=-a∑n_1E_1/∑n_1(A)+b (1) V_(A-H)=-c∑n_1E_1/∑n~(B)+d (2)利用上式计算的振动频率V_(A-H)值接近于文献值。从而验证了用韩长日方法计算电负性的合理性。
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| 关 键 词： | 共价型分子氢化物 振动频率 电负性 中性原子价层轨道能 |
RELATIONSHIP BETWEEN THE ENERGY OF VALENCE ORBITS OF ATOMS AND THE VIBRATIONAL FREQUENCE OF THE CHEMICAL BOND A-H IN THE COVALENT MOLECULAR HYDEIDES |
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| Yu Dian.RELATIONSHIP BETWEEN THE ENERGY OF VALENCE ORBITS OF ATOMS AND THE VIBRATIONAL FREQUENCE OF THE CHEMICAL BOND A-H IN THE COVALENT MOLECULAR HYDEIDES[J].Journal of Hubei Normal University(Philosophy and Social Science),1992(6). |
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| Authors: | Yu Dian |
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| Institution: | Chongqing Teachers College |
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| Abstract: | |
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| Keywords: | covalent molecular hydrides vibrational frequency electronegativity energy of valence orbits of neutral atoms |
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