| Abstract: | Six years of rainfall-event pH measurements from the nine-station MAP3S/PCN monitoring network in the eastern United States were analyzed. The initial objective was an attempted validation of the model developed by Eynon and Switzer (1983, Canad. J. Statist. 11, 11–24) on this independent data set. Because some features of the structure presumed in the model are not evident in this data set, the underlying structure of the data was then explored in some detail. Both aspects of the investigation confirmed that the identification of an appropriate statistical model for such data is a difficult undertaking; anticipated structure may not be evident, and the data corresponding to specific stations or years may exhibit anomalous behavior. |
