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Time series analysis of stratospheric ozone
Authors:DS St John  SP Bailey  WH Fellner  JM Minor  RD Snee  EI du Pont de
Institution:1. Petrochemicals Department , Experimental Station;2. Engineering Department , Louviers Building;3. Nemours and Company , Wilmington, Delaware, 19898
Abstract:Time series analyses of monthly average total ozone measured at 37 stations throughout the world were used to estimate the extent to which the average ozone trend correlates with the depletion curve hypothesized as due to chlorofluorocarbons (CFCs). Statistical characteristics of stations in the ensemble were used to help define appropriate model and station selection criteria. The maximum likelihood procedure developed herein estimates the weighted average trend, its. variance, and the intra- and inter-station variance components of the trend. Correlations among trends at different stations are also taken into account. The models were subjected to much checking and criticism. Variations in statistical methodology are used to show that the results are insensitive to details of the model selection criteria. The method does not discriminate well between the hypothesized CFC trend and a linear trend. The trend estimates represent the sum of all long-term global effects. The variance includes all effects that differ from station-to-station. The estimated trend and 2α limits for 14 stations with 20-year records (1958-79) is an ozone increase through 1979 of (1.5+1.0) percent. At the 23 stations with shorter records, the trend is (1.0=1.7) percent. It is concluded that no significant depletion in stratospheric ozone has occurred from any cause through the end of 1979.
Keywords:autoregressive process  chlorofluoro-carbon ozone effects  variance components  model evaluation  maximum likelihood averaging
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