| 六次甲基四胺合钴（Ⅱ）配合物的室温固相合成及其热色性 |
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| 引用本文： | 欧秀明,潘荣楷,石晓波.六次甲基四胺合钴（Ⅱ）配合物的室温固相合成及其热色性[J].湛江师范学院学报,2008,29(3):65-68. |
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| 作者姓名： | 欧秀明 潘荣楷 石晓波 |
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| 作者单位： | 湛江师范学院化学科学与技术学院,广东湛江524048 |
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| 基金项目： | 湛江师范学院校科研和教改项目 |
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| 摘 要： | 以六水合二氯化钴与六次甲基四胺为原料通过室温固相反应制得了钴（Ⅱ）-六次甲基四胺配合物，采用化学分析、IR、DTA和TG等手段对合成产物进行了袁征．并与液相合成法进行了比较，结果表明：配合物中Co（Ⅱ）与六次甲基四胺的物质的量之比为1：2，将六水合二氯化钴与六次甲基四胺以不同比例混合反应，所得的产物组成都为CoCl2·2C6H12N4·6H2O，该配合物具有良好的热致变色性能．
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| 关 键 词： | 固相反应 二氯化钴 六次甲基四胺 配位热色性 |
Room Temperature Solid State Synthesis and Thermochromism of the Hexamethylenetetramine Complexes with Cobalt (Ⅱ) |
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| OU Xiu-ming,PAN Rong-kai,SHI Xiao-bo.Room Temperature Solid State Synthesis and Thermochromism of the Hexamethylenetetramine Complexes with Cobalt (Ⅱ)[J].Journal of Zhanjiang Normal College,2008,29(3):65-68. |
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| Authors: | OU Xiu-ming PAN Rong-kai SHI Xiao-bo |
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| Institution: | (School of Chemical Science and Technology, Zhanjiang Normal University, Zhanjiang, Guangdong 524048,China) |
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| Abstract: | . COCl2 · 2C6 H12N4 · 6H2 O was synthesized by room temperature solid state process with cobalt（Ⅱ） chloride and hexamethylenetetramine. The compound was characterized by chemical analysis,IR, DTA-TG, etc. and was compared with that by liquid phase reactionprocess. The results showed that mole ratio of cobatt（Ⅱ） to hexamethylenetetramine for the complex was 1 ： 2 although the different reacts ratio The complexes have reversible thermochromatic properties. |
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| Keywords: | solid state reaction cobalt （Ⅱ） chloride hexamethylenetetramine coordination thermochromism |
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