| 高内相比乳液模板法制备高吸油性树脂 |
| |
| 引用本文： | 谭志,陈厚,范丽君,郝志海.高内相比乳液模板法制备高吸油性树脂[J].鲁东大学学报,2013(2):134-138. |
| |
| 作者姓名： | 谭志 陈厚 范丽君 郝志海 |
| |
| 作者单位： | 鲁东大学化学与材料科学学院,山东烟台264039 |
| |
| 基金项目： | 山东省科技发展计划项目（2009GGl0003012） |
| |
| 摘 要： | 以1-十八烯为单体,季戊四醇四丙烯酸酯为交联剂,偶氮二异丁腈为引发剂,Span80为乳化剂,环己烷为致孔剂,加入无机盐氯化钙,采用油包水高内相比乳液模板法合成了长链烯烃高吸油性树脂,并研究了其对氯仿的吸附性能.考察了交联剂、反应时间、引发剂、乳化剂、聚合温度、水相体积等因素对该树脂吸油性能的影响.得到了合成高吸油性树脂的最佳条件,所得高吸油性树脂对氯仿的吸油率为27 g/g.
|
| 关 键 词： | 1-十八烯 高内相比乳液 高吸油性树脂 |
Synthesis of High Oil-Absorbing Resins by High Internal Phase Emulsion Template |
| |
| TAN Zhi,CHEN Hou,FAN Li-jun,HAO Zhi-hai.Synthesis of High Oil-Absorbing Resins by High Internal Phase Emulsion Template[J].Ludong University Journal (Natural Science Edition),2013(2):134-138. |
| |
| Authors: | TAN Zhi CHEN Hou FAN Li-jun HAO Zhi-hai |
| |
| Institution: | (School of Chemistry and Materials Science, Ludong University,Yantai 264039, China) |
| |
| Abstract: | Adding inorganic salt anhydrous calcium chloride to the emulsion systems, with 1-octadecene as the monomer, pentaerythritol tetraacrylate as cross-linking agent, 2,2＇-azobisisobutyronitrile as initiator, Span80 as emulsifier, eyclohexane as porogen, respectively, high oil-absorbing resins were synthesized by high internal phase emulsion template. The adsorption property of the high oil-absorbing resins for chloromethane was stud- ied. Effects of cross-linking agent, reaction time, water volume fraction, initiator, emulsifier and temperature on the property of the high oil-absorbing resins were also studied. The optimum polymerization conditions for syn- thesis of high oil-absorbing resin were obtained. The highest oil absorbency of the resin for trichloromethane was 27g/g |
| |
| Keywords: | l-octadecene high internal phase emulsion ：high oil-absorntion resin |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
