负载型铑催化剂催化苯乙酮的多相不对称氢化反应的研究

研究了苯乙酮在负载型铑催化剂催化下的多相不对称氢化反应,结果表明在以1%Rh-γ-Al2O3-2TPPTS和1%Rh-SiO2-2TPPTS为催化剂,(1S,2S)-二苯基乙二胺(DPEN)为手性修饰剂和一定量的KOH用于苯乙酮的不对称加氢反应,在反应条件为40oC,5MpaH2下,显示出好的催化活性,苯乙酮加氢产物的对映选择性分别达到了22.5%和25.4%。     

青少年法制教育应确立新思路

新时期的青少年法制教育必须注入全新的理念 ,使法制教育成为素质教育的一部分 ,应在法制教育的同时加强对青少年权利义务观念、信用意识、科学精神的培养 ,并使青少年认识到法律的价值所在 ,才能培养自觉的守法精神。     

Unresolved Conflicts in the Regional Security System: The Case of the South Caucasus

The collapse of the USSR was accompanied by transformation of the South Caucasian latent ethnopolitical conflicts into local wars. Today the situation in the area of the conflicts is “neither war, nor peace”. Three unresolved conflicts of the South Caucasus can be considered as one of the most serious obstacles for establishing a regional security system.The article gives the general characteristics of these conflicts, the trends of their development, taking into account the time factor, and analyzes the behavioral models of the main players – de jure recognized and unrecognized de facto states of the South Caucasus. The basic objective of the main players should be to keep the situation on a level preventing the resumption of the armed conflicts. The attempts of forced resolution of the conflicts are fraught with destabilization of the situation not only in the area of any of these conflicts but in the whole region.     

土地治权的变动与政权变迁

在传统农耕社会的制度框架中,土地不仅是一种经济学意义上的自然资源,更为重要的是作为一种政治活动的对象而存在。国家以政权的形式赋予土地所有权、土地经营方式以合法性的依据。土地治权与国家政权之间存在着一种内在的张力,土地治权作为国家意志在土地之中的凝结,其变动是对于社会利益的一种强制性的分割,与传统社会的政权变动有着内在性的相关。     

Generalized quasi-likelihood

The quasi-score function, as defined by Wedderburn (1974) and McCullagh (1983) and so on, is a linear function of observations. The generalized quasi-score function introduced in this paper is a linear function of some unbiased basis functions, where the unbiased basis functions may be some linear functions of the observations or not, and can be easily constructed by the meaning of the parameters such as mean and median and so on. The generalized quasi-likelihood estimate obtained by such a generalized quasi-score function is consistent and has an asymptotically normal distribution. As a result, the optimum generalized quasi-score is obtained and a method to construct the optimum unbiased basis function is introduced. In order to construct the potential function, a conservative generalized estimating function is defined. By conservative, a potential function for the projected score has many properties of a log-likelihood function. Finally, some examples are given to illustrate the theoretical results. This paper is supported by NNSF project (10371059) of China and Youth Teacher Foundation of Nankai University.     

Ideas versus ideology: The origins of modern labor economics

Starting with its early twentieth century origins, the development of Labor Economics is traced to the present. We describe an intellectual revolution in which an earlier tra-dition that focused primarily on the institution of the labor union has been replaced by a perspective that emphasizes the various roles played by labor markets in an eco-nomic system. That earlier tradition contained very significant ideological elements, whereas its successor deals much more with the world of ideas. In the course of the debate, which still continues, ideas triumphed over ideology and created modern Labor Economics.     

城市公共空间与大众健康--19世纪英国城市公园发展的启示

在城市发展和改造过程中,英国近代城市先后着手进行城市公共空间———公园建设,从而掀起了一场造园运动。这场运动既是英国城市发展的必然结果,同时也是解决城市环境问题、提高大众健康水平的需要。而公园等公共空间的建设,为居民提供了一个锻炼与休闲的空间,有利于提高居民的健康水平。健康的人居环境,为各阶层民众提供了聚会的场所,体现了社会成员和谐相处的精神,成为英国资本主义成熟的重要表现之一。     

Flipping and ex post aggregation

We show that Bayesian ex post aggregation is unstable with respect to refinements. Suppose a group of Bayesians use ex post aggregation. Since it is a joint problem, each agent's problem is captured by the same model, but probabilities and utilities may vary. If they analyze the same situation in more detail, their refined analysis should preserve their preferences among acts. However, ex post aggregation could bring about a preference reversal on the group level. Ex post aggregation thus depends on how much information is used and may keep oscillating (“flipping”) as one keeps adding more information. Received: 16 April 2002/Accepted: 27 May 2002