悬汞电极阴极溶出伏安法测定人发中的痕量硒

本工作用悬汞电极—示波极谱仪研究了Se(Ⅳ)在HClO_4—KI—EDTA底液中的阴极溶出测定的。在选定条件下,Se(Ⅳ)于—0.5V左右产生一灵敏的导数波,灵敏度为5×10~(-10)M(0.04ppb)。Se(Ⅳ)件浓度在1×10~(-7)M～5×10~(-9)M间与峰电流呈良好线性关系。本法用于人发中痕量硒的测定,结果满意。     

用跳马步系列研究奇素数阶规则完美幻方的个数

本文先介绍跳马步系列的有关概念及性质,然后用跳马步系列研究奇素数阶规则完美幻 方的个数。     

Using p values to design statistical process control charts

Conventional Phase II statistical process control (SPC) charts are designed using control limits; a chart gives a signal of process distributional shift when its charting statistic exceeds a properly chosen control limit. To do so, we only know whether a chart is out-of-control at a given time. It is therefore not informative enough about the likelihood of a potential distributional shift. In this paper, we suggest designing the SPC charts using p values. By this approach, at each time point of Phase II process monitoring, the p value of the observed charting statistic is computed, under the assumption that the process is in-control. If the p value is less than a pre-specified significance level, then a signal of distributional shift is delivered. This p value approach has several benefits, compared to the conventional design using control limits. First, after a signal of distributional shift is delivered, we could know how strong the signal is. Second, even when the p value at a given time point is larger than the significance level, it still provides us useful information about how stable the process performs at that time point. The second benefit is especially useful when we adopt a variable sampling scheme, by which the sampling time can be longer when we have more evidence that the process runs stably, supported by a larger p value. To demonstrate the p value approach, we consider univariate process monitoring by cumulative sum control charts in various cases.     

An Empirical Study of Statistical Properties of Variance Partition Coefficients for Multi-Level Logistic Regression Models

Partitioning the variance of a response by design levels is challenging for binomial and other discrete outcomes. Goldstein (2003 Goldstein , H. ( 2003 ). Multilevel Statistical Models. 3rd ed . London : Edward Arnold . [Google Scholar]) proposed four definitions for variance partitioning coefficients (VPC) under a two-level logistic regression model. In this study, we explicitly derived formulae for multi-level logistic regression model and subsequently studied the distributional properties of the calculated VPCs. Using simulations and a vegetation dataset, we demonstrated associations between different VPC definitions, the importance of methods for estimating VPCs (by comparing VPC obtained using Laplace and penalized quasilikehood methods), and bivariate dependence between VPCs calculated at different levels. Such an empirical study lends an immediate support to wider applications of VPC in scientific data analysis.     

Comparison of Confidence Intervals on Between Group Variance in Unbalanced Heteroscedastic One-Way Random Models

A computer algorithm for computing the alternative distributions of the Wilcoxon signed rank statistic under shift alternatives is discussed. An explicit error bound is derived for the numeric integration approximation to these distributions.

A nonparametric process control procedure in which the standard CUSUM procedure is applied to the Wilcoxon signed rank statistic is discussed. In order to implement this procedure, the distribution of the Wilcoxon statistic under shift of the underlying distribution from its point of symmetry needs to be computed. The average run length of the nonparametric and parametric CUSUM are compared.     

Positive False Discovery Rate Estimate in Step-Wise Variable Selection

Selecting predictors to optimize the outcome prediction is an important statistical method. However, it usually ignores the false positives in the selected predictors. In this article, we advocate a conventional stepwise forward variable selection method based on the predicted residual sum of squares, and develop a positive false discovery rate (pFDR) estimate for the selected predictor subset, and a local pFDR estimate to prioritize the selected predictors. This pFDR estimate takes account of the existence of non null predictors, and is proved to be asymptotically conservative. In addition, we propose two views of a variable selection process: an overall and an individual test. An interesting feature of the overall test is that its power of selecting non null predictors increases with the proportion of non null predictors among all candidate predictors. Data analysis is illustrated with an example, in which genetic and clinical predictors were selected to predict the cholesterol level change after four months of tamoxifen treatment, and pFDR was estimated. Our method's performance is evaluated through statistical simulations.     

A multiple-case deletion approach for detecting influential points in high-dimensional regression

ABSTRACT

In high-dimensional regression, the presence of influential observations may lead to inaccurate analysis results so that it is a prime and important issue to detect these unusual points before statistical regression analysis. Most of the traditional approaches are, however, based on single-case diagnostics, and they may fail due to the presence of multiple influential observations that suffer from masking effects. In this paper, an adaptive multiple-case deletion approach is proposed for detecting multiple influential observations in the presence of masking effects in high-dimensional regression. The procedure contains two stages. Firstly, we propose a multiple-case deletion technique, and obtain an approximate clean subset of the data that is presumably free of influential observations. To enhance efficiency, in the second stage, we refine the detection rule. Monte Carlo simulation studies and a real-life data analysis investigate the effective performance of the proposed procedure.     

Random sampling from the watson distribution

An envelope-rejection method is used to generate random variates from the Watson distribution. The method is compact and is competitive with, if not superior to, the existing sampling algorithms. For the girdle form of the Watson distribution, a faster algorithm is proposed. As a result, Johnson's sampling algorithm for the Bingham distribution is improved.     

An Extension of Economic Design of x-Bar Control Charts for Non Normally Distributed Data Under Weibull Shock Models

Three parameters—sample size, sampling intervals, and the control limits—must be determined when the x bar chart to monitor a manufacturing process. The constant sampling intervals were widely employed because of its administrative simplicity. However, the variable sampling interval (VSI) has recently been shown to give substantially faster detection of most process shifts than fixed-sampling-interval (FSI) for x-bar charts. In addition, these measurements in the subgroup are assumed to be normally distributed. That assumption may not be tenable. This investigation compares the economic design of x-bar control charts for non normal data under Weibull shock models with various sampling avenues.     

Testing for the Equality of Two Autoregressive Functions Using Quasi-Residuals

This article discusses the problem of testing the equality of two nonparametric autoregressive functions against one-sided alternatives. The heteroscedastic errors and stationary densities of the two independent strong mixing strictly stationary time series can be possibly different. The article adapts the idea of using sum of quasi-residuals to construct the test and derives its asymptotic null distributions. The article also shows that the test is consistent for general alternatives and obtains its limiting distributions under a sequence of local alternatives. Then a Monte Carlo simulation is conducted to study the finite sample level and power behavior of these tests at some alternatives. We also compare the test to an existing lag matched test theoretically and by Monte Carlo experiments.