高速火焰喷涂Fe-Al/Cr3C2复合涂层的组织及冲蚀性能研究

采用高速火焰喷涂方法,喷涂材料选用自主研发的F e-A l/C r3C2粉材,在20钢基体上制备复合涂层.分析涂层的组织,并对涂层的抗冲蚀磨损性能进行研究.结果表明,高速火焰喷涂F e-A l/C r3C2复合涂层中主要包括F e3A l、C r3C2以及-αF e相,C r3C2增强相呈点状均匀分布于涂层的层片状结构中.涂层与基体间及涂层内部主要是机械结合.涂层的冲蚀特性在300℃、450℃、650℃时分别主要为脆性冲蚀、塑性冲蚀-脆性冲蚀、塑性冲蚀;冲蚀角度对涂层的耐冲蚀性能有较大影响,30°时涂层的抗冲蚀能力优于90°时;温度升高,涂层的抗冲蚀性能提高.     

Modifying and using Yates' algorithm

It is well known that Yates' algorithm can be used to estimate the effects in a factorial design. We develop a modification of this algorithm and call it modified Yates' algorithm and its inverse. We show that the intermediate steps in our algorithm have a direct interpretation as estimated level-specific mean values and effects. Also we show how Yates' or our modified algorithm can be used to construct the blocks in a 2 ^k factorial design and to generate the layout sheet of a 2 ^k−p fractional factorial design and the confounding pattern in such a design. In a final example we put together all these methods by generating and analysing a 2^6-2 design with 2 blocks.     

Bayesian confidence interval for difference of the proportions in a 2×2 table with structural zero

This article studies the construction of a Bayesian confidence interval for risk difference in a 2×2 table with structural zero. The exact posterior distribution of the risk difference is derived under the Dirichlet prior distribution, and a tail-based interval is used to construct the Bayesian confidence interval. The frequentist performance of the tail-based interval is investigated and compared with the score-based interval by simulation. Our results show that the tail-based interval at Jeffreys prior performs as well as or better than the score-based confidence interval.     

渗流驱动问题的多步特征有限元方法

不可压缩可混溶驱动问题的数学模型是由椭圆型压力方程和抛物型饱和度方程偶合而成的非线性偏微分方程组.用有限元法离散压力方程,向后多步特征有限元法离散饱和度方程,提高了时间误差阶,并得到与单步特征有限元法相同的L2(Ω)模先验误差估计.     

掺Ni、Co、Cr、V的TiO2纳米粒子制备与表征

采用两种不同方法制备TiO2纳米粒子,即以钛酸四正丁酯为原料,用溶胶-凝胶法制备掺Ni的TiO2纳米粒子.以硫酸钛和碳酸铵为原料,用沉淀法制备掺Ni、Co、Cr、V的TiO2纳米粒子,并且对两种制备方法进行了对比.利用TG-DTA,FTIP,SEM和PL光谱测试技术对样品进行了表征.结果表明制备条件的不同对样品性能有很大影响.     

2-乙基己基膦酸单2-乙基己基酯的分配常数和二聚常数的测定

采用较为简单且快速的两相滴定法测定了酸性磷型萃取剂2-乙基已基膦酸单2-乙基已基酯在水和有机溶剂之间的分配常数和二聚常数,并编制了计算机程序处理实验数据,所得结果可靠。     

民进党执政后的台湾经济态势分析

民进党上台四年来,台湾经济从中速发展逆转为负增长和低速增长,处于衰退和低迷之中。其原因主要在于:内部政局和社会动荡影响投资者的投资意愿;台湾当局以"台独"意识形态处理海峡两岸关系,使两岸关系僵局无法缓解,外资对台投资大量减少;近两年国际经济不景气,使台湾出口贸易受阻,只依赖对中国大陆和香港的出口增长来维持其经济正增长的局面。前两个因素如果不解决好,台湾经济要恢复到过去的中速增长是困难的。     

铜(Ⅱ)盐催化2,4,6—三溴间甲苯酚聚合反应动力学研究

研究了各种条件下铜(Ⅱ)盐催化2,4,6—三溴间甲苯酚聚合反应的动力学.当[CuCl_2]<0.05mol/L时,r-(k_1k_2)/(k-1)[2,4,6—三溴间甲苯酚][CH_3ONa][CuCl_2];当[CuCl_2>0.05mol/L时,γ=(k_1k_2)/(k-1)[2,4,6 —三溴间甲苯酚][CH_3ONa][0.10-[CuCl_2]);实验所得的速度方程式与铜(Ⅱ) —酚氧配合物中间体形成机理相一致.决定反应速度步骤为2,4,6—三溴间甲苯酚钠与铜(Ⅱ)盐配合物的反应,并且由实验求得了反应速度常数及反应的活化能.     

Statistical consequences of an adaptive treatment allocation in a clinical trial

An examination of the likelihood arising from data in experiments comparing two therapies for neonatal respiratory failure illustrates a difficulty in the use of a design with adaptive treatment allocation as opposed to the use of the classical fixed-sample-size design. The requirement of obtaining objective scientific evidence as to which treatment is better for use on future patients conflicts with attempts to give the treatment thought to be the best to the patient at hand.