卤化物的稳定性

本文利用热力学原理,计算晶格能和自由能变,根据晶格能及自由能变来判断离子型卤化物的稳定性。     

Bayesian factor models in characterizing molecular adaptation

Assessing the selective influence of amino acid properties is important in understanding evolution at the molecular level. A collection of methods and models has been developed in recent years to determine if amino acid sites in a given DNA sequence alignment display substitutions that are altering or conserving a prespecified set of amino acid properties. Residues showing an elevated number of substitutions that favorably alter a physicochemical property are considered targets of positive natural selection. Such approaches usually perform independent analyses for each amino acid property under consideration, without taking into account the fact that some of the properties may be highly correlated. We propose a Bayesian hierarchical regression model with latent factor structure that allows us to determine which sites display substitutions that conserve or radically change a set of amino acid properties, while accounting for the correlation structure that may be present across such properties. We illustrate our approach by analyzing simulated data sets and an alignment of lysin sperm DNA.     

Multivariate Kendall's tau for change‐point detection in copulas

Statistical procedures for the detection of a change in the dependence structure of a series of multivariate observations are studied in this work. The test statistics that are proposed are $L_1$ , $L_2$ , and $L_{\infty }$ distances computed from vectors of differences of Kendall's tau; two multivariate extensions of Kendall's measure of association are used. Since the distributions of these statistics under the null hypothesis of no change depend on the unknown underlying copula of the vectors, a procedure based on the multiplier central limit theorem is used for the computation of p‐values; the method is shown to be valid both asymptotically and for moderate sample sizes. Alternative versions of the tests that take into account possible breakpoints in the marginal distributions are also investigated. Monte Carlo simulations show that the tests are powerful under many scenarios of change‐point. In addition, two estimators of the time of change are proposed and their efficiency is carefully studied. The methodologies are illustrated on simulated series from the Canadian Regional Climate Model. The Canadian Journal of Statistics 41: 65–82; 2013 © 2012 Statistical Society of Canada     

中国居民收入分布专题实证研究——居民收入分布变迁测度及其影响因素分解

基于核密度估计方法,给出居民收入分布变迁测度及其影响因素分解的相对收入分布方法。使用中国健康和营养调查的微观居民收入数据,实证分析中国居民收入分布及其变迁的特征、过程及其影响因素。实证结果显示:中国居民收入分布变迁的速度与经济体制改革进程相对应;经济增长因素是引起居民收入分布变迁的主要因素,在提高总体居民收入水平的同时加剧了居民收入分布的极化程度;收入分配因素对居民收入分布变迁的作用相对较弱,但有一定的减贫或缩小居民收入差距作用。     

Storage Life Prediction for a High-Performance Capacitor Using Multi-Phase Wiener Degradation Model

Capacitance is a critical performance characteristic of high-voltage-pulse capacitor which is used to store and discharge electrical energy rapidly. The capacitors usually are stored for a long period of time before put into use. Experimental result and engineering experience indicate that the capacitance increases with storage time and will eventually exceed the failure threshold, which means that the capacitor may fail during storage. This is a typical mode of degradation failure for long storage products. Further, the capacitance degradation path can be extrapolated in several stages based on the shifting characteristics. That is, the capacitance increases slowly or fluctuates in the initial storage stage that lasts about three months. Then it increases sharply in the middle stage which lasts about four months. After the two stages, the capacitor enters into the third stage in which capacitance increases constantly. This degradation phenomenon motivates us to study the storage life prediction method based on multi-phase degradation path model. The storage performance degradation mechanism of high-voltage-pulse capacitor was investigated, which provides the physical basis for multi-phase Wiener degradation model. Identification procedure for the transition points in the degradation path was proposed using maximum likelihood principle (MLP). The result of Kruskal-Wallis test which is the method to test whether two populations are consistent or not in statistics showed that the transition points are statistically effective. Other parameters in the multi-phase degradation model are estimated with maximum likelihood estimation (MLE) after the transition points have been specified. The multi-phase Inverse Gaussian (IG) distribution for storage life was deduced for the capacitor, and the point and interval estimation procedure for reliable storage life are constructed with bootstrap method. The efficiency and effectiveness of the proposed multi-phase degradation model is compared with storage life prediction under single-phase condition.     

Income vulnerability of rural households in Bangladesh: a comparison between Bayesian and classical methods

The geographical location and the monsoon climate render Bangladesh highly vulnerable to natural hazards, deteriorating the country's socio-economic stability. This study is based on 500 randomly chosen rural households from the Household Income and Expenditure Survey [Bangladesh Bureau of Statistics, Planning Division, Ministry of Planning, Government of the People's Republic of Bangladesh, Dhaka, 2006]. The objectives are to estimate the income vulnerability of rural households and to check whether the Bayesian approaches (natural conjugate prior and non-informative prior estimates) have any superiority over the classical (feasible generalized least square (FGLS)) method. The poverty level, measured from the data, is 24%; whereas the vulnerability estimates, using FGLS, natural conjugate prior and non-informative prior are 31%, 69% and 82%, respectively. Vulnerability estimates by the Bayesian natural conjugate prior approach is found to have greater efficiency compared with FGLS and non-informative prior approaches.     

On Locating and Characterizing Parameter Variation by the Mosumsq Test Statistic

In modelling a system structure it is often important to test the constancy of the structural parameters. If the hypothesis of constant parameters is rejected we wish to characterize the parameter variation. In this paper we examine the usefulness of the MOSUMSQ test statistics for locating and characterizing the parameter variation in linear regression models. The means and the variances of the test statistics are given for non-random parameter variation. The observed path of the MOSUMSQ test statistics provides valuable knowledge about the time of the onset of the parameter change and whether it is instantaneous or gradual.     

Test for Parameter Change in Linear Processes Based on Whittle's Estimator

In this article, we develop a cusum test for testing for parameter changes in linear processes based on Whittle's estimator. It is shown that under regularity conditions, the test statistic converges to the sup of a Brownian bridge. The result is particularly useful in handling the change point test in stationary ARMA processes. A simulation result is provided for illustration.     

Estimating the mean of the selected uniform population

Let π_i(i=1,2,…K) be independent U(0,?_i) populations. Let Y_i denote the largest observation based on a random sample of size n from the i-th population. for selecting the best populaton, that is the one associated with the largest ?_i, we consider the natural selection rule, according to which the population corresponding to the largest Y_i is selected. In this paper, the estimation of M. the mean of the selected population is considered. The natural estimator is positively biased. The UMVUE (uniformly minimum variance unbiased estimator) of M is derived using the (U,V)-method of Robbins (1987) and its asymptotic distribution is found. We obtain a minimax estimator of M for K≤4 and a class of admissible estimators among those of the form cY_max. For the case K = 2, the UMVUE is improved using the Brewster-Zidek (1974) Technique with respect to the squared error loss function L₁ and the scale-invariant loss function L₂. For the case K = 2, the MSE'S of all the estimators are compared for selected values of n and ρ=?₁/(?₁+?₂).