Mathematische aspekte zu einer methode zur numerischen bestimmung individueller thermodynamischer aktivitätskoeffizienten einzelner ionensorten in konzentrierten elektrolytlösungen

The mathematical problems of the – in an communication [3] described – principle for the calculation of individual thermodynamic activity coefficients of single ionic species in concentrated electrolyte solutions are specified. It is the Newtonian approximation method that makes possible the evaluation of the constants b ₁,…b ₄ in the concentration function (0.1) for the product of the activity coefficients.

The efficiency of the method is represented by the example of the activity coefficients of pure and of – with other electrolytes – mixed solutions of NaCIO₄. The individual activity coefficients of the single ionic species are evaluated for several electrolytes of the concentration range from m = 0 to m = 10 mole/kg and published at another place [3, 17, 18].     

Bounded influence estimation for regression and scale

Bednarski and Müller [Optimal bounded influence regression and scale M-estimators in the context of experimental design, Statistics 35 (2001), pp. 349–369] introduced a class of bounded influence M estimates for the simultaneous estimation of regression and scale in the linear model with normal errors by solving the corresponding normal location and scale problem at each design point. This limits the proposal to regressor distributions with finite support. Based on their approach, we propose a slightly extended class of M estimates that is not restricted to finite support and is numerically easier to handle. Moreover, we employ the even more general class of asymptotically linear (AL) estimators which, in addition, is not restricted to normal errors. The superiority of AL estimates is demonstrated by numerical comparisons of the maximum asymptotic mean-squared error over infinitesimal contamination neighbourhoods.     

Strong consistency of least squares estimates with i.i.d. errors with mean values not necessarily defined

We establish strong consistency of the least squares estimates in multiple regression models discarding the usual assumption of the errors having null mean value. Thus, we required them to be i.i.d. with absolute moment of order r, 0<r<2, and null mean value when r>1. Only moderately restrictive conditions are imposed on the model matrix. In our treatment, we use an extension of the Marcinkiewicz–Zygmund strong law to overcome the errors mean value not being defined. In this way, we get a unified treatment for the case of i.i.d. errors extending the results of some previous papers.     

Analysis of hybrid censored competing risks data

In this paper, we consider the analysis of hybrid censored competing risks data, based on Cox's latent failure time model assumptions. It is assumed that lifetime distributions of latent causes of failure follow Weibull distribution with the same shape parameter, but different scale parameters. Maximum likelihood estimators (MLEs) of the unknown parameters can be obtained by solving a one-dimensional optimization problem, and we propose a fixed-point type algorithm to solve this optimization problem. Approximate MLEs have been proposed based on Taylor series expansion, and they have explicit expressions. Bayesian inference of the unknown parameters are obtained based on the assumption that the shape parameter has a log-concave prior density function, and for the given shape parameter, the scale parameters have Beta–Gamma priors. We propose to use Markov Chain Monte Carlo samples to compute Bayes estimates and also to construct highest posterior density credible intervals. Monte Carlo simulations are performed to investigate the performances of the different estimators, and two data sets have been analysed for illustrative purposes.     

Asymptotic results for random coefficient bifurcating autoregressive processes

The purpose of this paper is to study the asymptotic behaviour of the weighted least-squares estimators of the unknown parameters of random coefficient bifurcating autoregressive processes. Under suitable assumptions on the immigration and the inheritance, we establish the almost sure convergence of our estimators, as well as a quadratic strong law and central limit theorems. Our study mostly relies on limit theorems for vector-valued martingales.     

Model averaging for M-estimation

M-estimation is a widely used technique for robust statistical inference. In this paper, we study model selection and model averaging for M-estimation to simultaneously improve the coverage probability of confidence intervals of the parameters of interest and reduce the impact of heavy-tailed errors or outliers in the response. Under general conditions, we develop robust versions of the focused information criterion and a frequentist model average estimator for M-estimation, and we examine their theoretical properties. In addition, we carry out extensive simulation studies as well as two real examples to assess the performance of our new procedure, and find that the proposed method produces satisfactory results.     

On the construction of optimal experimental designs: a penalty approach

Tn optimal experimental design theory there are well-known situations, in which additional constraints are implied to the design set. These constraints destroy in general the simplex structure of the set of feasible points of the design set. Thus the available iteration procedures for the unrestricted case are no longer applicable.

In this paper a penalty approach is suggested which transforms the restricted problem to the unrestricted case and allows the application of well-known algorithms such as the Fedorov-Wynn-type or the projected gradient procedure.     

Modified minimax estimation of regression coefficients

Working with the linear regression model (1.1) and having the extraneous information (1.2) about regression coefficients the problem exists how to build estimators (1.3) with the risk (1.4) which enable to utilize the known information in order to reduce their risk as compared with the risk (1.6) of the LSE (1.5). Solution of this problem is known for the positive definite matrix T, namely in form for estimators (1.8) and (1.10).First, it is shown that the proposed estimators (2.6),(2.9) and (2.16) based on psedoinversions of the matrix L represent the solution of the problem of the positive semidefinite matrix T=L'L.Further, the problem of interpretability of estimators in the sense of the inequality (3.1) exists; it is shown that all mentioned estimators are at least partially interpretable in the sense of requirements (3.2) or (3.10).     

On the cohen-sackrowitz estimator of a common mean

The paper reconsider certain estimators proposed by COHENand SACKROWITZ[Ann.Statist.(1974)2,1274-1282,Ann.Statist.4,1294]for the common mean of two normal distributions on the basis of independent samples of equal size from the two populations. It derives the ncecessary and sufficient condition for improvement over the first sample mean, under squared error loss, for any member of a class containing these. It shows that the estimator proposded by them for simultaneous improvement over botyh sample means has the desired property if and only if the common size of the samples is at least nine. The requirement is milder than that for any other estimator at the present state of knolwledge and may be constrasted with their result which implies the desired property of the estimator only if the common size of the samples is at least fifteen. Upper bounds for variances if the estimators derived by them are also improved     

Transformed Logit Confidence Intervals for Small Populations in Single Capture–Recapture Estimation

The good performance of logit confidence intervals for the odds ratio with small samples is well known. This is true unless the actual odds ratio is very large. In single capture–recapture estimation the odds ratio is equal to 1 because of the assumption of independence of the samples. Consequently, a transformation of the logit confidence intervals for the odds ratio is proposed in order to estimate the size of a closed population under single capture–recapture estimation. It is found that the transformed logit interval, after adding .5 to each observed count before computation, has actual coverage probabilities near to the nominal level even for small populations and even for capture probabilities near to 0 or 1, which is not guaranteed for the other capture–recapture confidence intervals proposed in statistical literature. Thus, given that the .5 transformed logit interval is very simple to compute and has a good performance, it is appropriate to be implemented by most users of the single capture–recapture method.