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温度对聚合物QCM传感器性能的影响研究
引用本文:应智花,蒋亚东,杜晓松,谢光忠.温度对聚合物QCM传感器性能的影响研究[J].电子科技大学学报(社会科学版),2008(6).
作者姓名:应智花  蒋亚东  杜晓松  谢光忠
作者单位:杭州电子科技大学电子信息学院;电子科技大学光电信息学院;电子科技大学电子薄膜与集成器件国家重点实验室;
基金项目:国家杰出青年基金(60425101); 国家自然科学基金重点项目(60736005)
摘    要:以聚偏氟乙烯(PVDF)为敏感材料,石英晶体微天平(QCM)为敏感元件构成聚合物QCM传感器。该文主要对神经毒剂模拟剂DMMP的气敏特性进行研究,并重点讨论了温度对PVDF聚合物膜层QCM传感器性能的影响。结果表明,当测试温度愈接近PVDF的玻璃化温度,传感器的响应幅值就愈高,且在各个DMMP测试气氛浓度时,传感器的响应幅值对温度的依赖性均符合Arrhenius关系;升高温度有利于提高传感器的响应速度,但同时其灵敏度却降低。

关 键 词:Arrhenius关系  聚偏氟乙烯  QCM传感器  温度  

Temperature Influence on Polymer Films Coated QCM Sensor Performances
YING Zhi-hua,JIANG Ya-dong,DU Xiao-song, XIE Guang-zhong.Temperature Influence on Polymer Films Coated QCM Sensor Performances[J].Journal of University of Electronic Science and Technology of China(Social Sciences Edition),2008(6).
Authors:YING Zhi-hua  JIANG Ya-dong  DU Xiao-song    XIE Guang-zhong
Institution:YING Zhi-hua1,JIANG Ya-dong2,DU Xiao-song2,, XIE Guang-zhong2 (1. Department of Electronics , Information,Hangzhou DIANZI University Hangzhou 310018,2. School of Optoelectronic Information,University of Electronic Science , Technology of China,State Key Laboratory of Electronic Thin Films , Integrated Devices,University of Electronic Science , Technology of China Chengdu 610054)
Abstract:Poly(vinylidene fluoride) (PVDF) modified quartz crystal microbalance(QCM) sensor has been prepared for DMMP vapor detection. The temperature influence on the performances of the sensor was emphatically investigated. The results show that the sensitivity of the sensor is higher with the working temperature closer to the glass transition temperature(Tg) of PVDF,and the absolute frequency responses of the PVDF coated QCM sensor all exhibit negative Arrhenius temperature dependency in spite of different vapor ...
Keywords:Arrhenius dependency  poly(vinylidene fluoride)  QCM sensor  temperature  
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