| 原子簇的合成方法、性质表征与结构 |
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| 引用本文： | 焦凤英,徐吉春,张新堂,殷元骐,Pierre Braunstein,JackyRose. 原子簇的合成方法、性质表征与结构[J]. 济南大学学报(社会科学版), 1996, 0(1) |
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| 作者姓名： | 焦凤英 徐吉春 张新堂 殷元骐 Pierre Braunstein JackyRose |
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| 作者单位： | 济南大学，中国科学院兰州化学物理研究所，中国科学院兰州化学物理研究所，中国科学院兰州化学物理研究所，Laboratoire de chimie de coordination，UA 416 CNRS，Universite Louis pasteur，4 rue Blaise Pascal，F—67070 strasbourg Cedex，France，Laboratoire de chimie de coordination，UA 416 CNRS，Universite Louis pasteur，4 rue Blaise Pascal，F—67070 strasbourg Cedex，France |
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| 摘 要： | 利用给电子有机和无机配位体的交换反应和金属卤化物与羰基金属阴离子的复分解反应,合成异核原子簇具有反应条件温和易于控制,收率较高的特点。本文描述Fe_3(CO)_9(C_2H_2)_3等11个原子簇的合成方法,配位状态与簇核的结构。
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| 关 键 词： | 异核原子簇 过渡金属羰基化合物 配合物 |
SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS |
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| Jiao FengYinJinan University,Jinan Xu Jichun Zhang Xintang Yin YuanqiLanzhou Institute of Chemical physics,Chinese Academy of Sciences,lanzhou Pierre Braunstein Jacky RoseLaboratoire de Chimie de coordination,UA CNRS,Universit'e Louis Pasteur, rue Blais pascal,F- Strasbourg Cedex,France. SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS[J]. Journal of Jinan University, 1996, 0(1) |
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| Authors: | Jiao FengYinJinan University Jinan Xu Jichun Zhang Xintang Yin YuanqiLanzhou Institute of Chemical physics Chinese Academy of Sciences lanzhou Pierre Braunstein Jacky RoseLaboratoire de Chimie de coordination UA CNRS Universit'e Louis Pasteur rue Blais pascal F- Strasbourg Cedex France |
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| Affiliation: | Jiao FengYinJinan University,Jinan 250002Xu Jichun Zhang Xintang Yin YuanqiLanzhou Institute of Chemical physics,Chinese Academy of Sciences,lanzhou 730000Pierre Braunstein Jacky RoseLaboratoire de Chimie de coordination,UA 416 CNRS,Universit'e Louis Pasteur,4 rue Blais pascal,F-67070 Strasbourg Cedex,France |
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| Abstract: | Exchang reaction of carbonyl with organic or inorganic ligands of electron-doner and metathesis of metal halids with carbonyl metal negative ion have been used to prepare some heteronuclear atomic clusters. The reaction condition are often moderate. They performed easier and have, a mord yield. In This paper, Synthesis, coordination slate, and framwork of cluster nuclear of Fe3(CO)9(C2H2)3 ect, which have 11 cluster, were described. |
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| Keywords: | heteronuclear duster transition metal carbonyl compound coordination complex |
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