| 单链晶体的平衡态分析 |
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| 引用本文： | 胡秀兰.单链晶体的平衡态分析[J].上海理工大学学报(社会科学版),1994(2). |
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| 作者姓名： | 胡秀兰 |
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| 作者单位： | 上海机械学院基础教学部 |
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| 摘 要： | 本文用统计力学的方法分析了单链晶体的平衡态．通过计算得到平衡态尺寸，平衡态尺寸与温度及单链的分子量有关．从单链晶体的热力学分析也得到了类似的平衡态尺寸表示式．比较两个结果，可从分子理论的基础上来理解单链晶体的侧表面自由能及折迭表面自由能．
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| 关 键 词： | 单链晶体，配分函数，自由能，平衡态 |
AN ANALYSIS OF THE EQUILIBRIUM STATE OF SINGLE-CHAIN CRYSTAL |
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| Hu Xiulan.AN ANALYSIS OF THE EQUILIBRIUM STATE OF SINGLE-CHAIN CRYSTAL[J].Journal of University of Shanghai For Science and Technilogy(Social Science),1994(2). |
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| Authors: | Hu Xiulan |
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| Abstract: | A statistical mechanical method is used to analyse the equilibrium state of single-chain crystal. The equilibrium dimension of single-chain crystal is calculated,and it is shown that the equilibrium dimension is related to temperature and the molar mass of single chain. A similar expression is also obtained from the thermodynamics analysis of single-chain. By comparing both results, an explanation of side and fold surface free energies can be found on molecular-theoretical grounds. |
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| Keywords: | Single-chain crystal Partition function Free energy Equilibrium state |
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