| 光学活性氰醇的不对称合成研究进展 |
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| 引用本文： | 翟志才,王贵才.光学活性氰醇的不对称合成研究进展[J].盐城工学院学报(社会科学版),2000(4). |
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| 作者姓名： | 翟志才 王贵才 |
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| 作者单位： | 盐城工学院化学工程系!江苏盐城224003(翟志才)，江苏省石化厅信息中心!江苏南京210024(王贵才) |
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| 摘 要： | 光学活性氰醇是合成大量医药、农药产品的重要中间体。介绍了用具有光学活性的生物或化学催化剂对前手性底物的不对称化来制备光学活性氰醇的方法 ,重点对 (S) α 氰基 3 苯氧基苯甲醇的不对称催化作了较为全面的概述 ,并对不对称合成的特点、机理及发展前景作扼要的介绍。
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| 关 键 词： | 光学活性 不对称合成 对映异构体 手性催化剂 |
Progress in the Asymmetric Synthesis of Optically Active Cyanohydrins |
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| ZHAI Zhi cai ,WANG Gui cai.Progress in the Asymmetric Synthesis of Optically Active Cyanohydrins[J].Journal of Yancheng Institute of Technology,2000(4). |
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| Authors: | ZHAI Zhi cai WANG Gui cai |
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| Institution: | ZHAI Zhi cai 1,WANG Gui cai 2 |
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| Abstract: | Optically active cyanohdrins are important intermediates for the synthesis of medical and agricultural chemicals. This article reviews the preparation of optically active cyanohydrins, which are formed by prochiral suitable substrates catalyzed by optically active biological or chemical catalysts. And the characteristic, the reaction mechanism and the prospect of asymmetric synthesis were also briefly described in this paper. |
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| Keywords: | optically active asymmetric synthesis enantiomeric isomer chiral catalyst |
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