| 乙酸正丁酯催化合成的探讨 |
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| 引用本文： | 金传明
,余新武
,陈才元
,杨水金
,龚楚儒.乙酸正丁酯催化合成的探讨[J].湖北师范学院学报(哲学社会科学版),1996(3). |
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| 作者姓名： | 金传明 余新武 陈才元 杨水金 龚楚儒 |
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| 摘 要： | 本文报道了新型催化剂Ti(Al)SiW_(12)O_(40)/TiO_2的制备方法,实验考察了该催化剂催化合成乙酸正丁酯的醇酸比、催化剂用量、带水剂,反应时间等因素对酯收率的影响。实验表明:在以苯为带水剂时催化剂的用量为反应液的0.36％,醇酸摩尔比为1.10:1,酯化反应时间为1.5hour,乙酸正丁酯的收率达79.0％,超过以浓硫酸、磷钨酸催化的水平。
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| 关 键 词： | Ti(Al)SiW_(12)O_(40)/TiO_2 催化 酯化反应 |
Research on Catalytic Esterification for Preparing Butyl of Acetic Acid with HPC-12 |
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| Jin Chuanming Yu Xinwu Chen Caiyuan Yang Shuijin Gong Churu.Research on Catalytic Esterification for Preparing Butyl of Acetic Acid with HPC-12[J].Journal of Hubei Normal University(Philosophy and Social Science),1996(3). |
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| Authors: | Jin Chuanming Yu Xinwu Chen Caiyuan Yang Shuijin Gong Churu |
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| Institution: | Hubei Normal University |
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| Abstract: | In this paper,HPC-12 Catalyst is prepared and is used as the catalyst for preparing butyl ester of acetic acid. The optimal condition are:more ratio of butyl alcohol to acetic acid 1. 10 : 1,the quantity of catalyst to feedstock 0. 36% (wt. ) ,hydrocarrying agent benzene and the reaction time 1. 5 hours. |
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| Keywords: | Ti(Al)SiW_12O_(40)/TiO_2 Catalysis Esterifieation reaction |
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