| 金属表面配位化学反应与成膜机理 |
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| 引用本文： | 李道华.金属表面配位化学反应与成膜机理[J].西昌学院学报(社会科学版),1999(3). |
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| 作者姓名： | 李道华 |
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| 作者单位： | Xichang，Sichuan 615022 |
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| 基金项目： | 国家自然科学基金(No 29631040)，江苏省自然科学基金(No BJ97039)资助项目 |
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| 摘 要： | 用FT—IR,F—IR,FT—Raman,XPS和AES研究镍表面Mo—S簇合物膜,结果表明,膜层中存在Mo—S—Ni、Mo—S—Mo和端基Mo—S键,膜是由MoS_2与Mo—S—Ni簇合物组成的多分子层,可描述为双层结构。阐述了表面配位化学反应中的成膜机理和影响配合物膜形成的因素。
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| 关 键 词： | 金属 表面化学反应 配合物膜 多分子层 单分子层 |
Surface Coordination Reactions on Metal and Mechanism for Films Formation |
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| Li Daohua.Surface Coordination Reactions on Metal and Mechanism for Films Formation[J].Journal of Xichang College :Social Science Edition,1999(3). |
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| Authors: | Li Daohua |
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| Institution: | Li Daohua Department of Chemistry,Xichang Teacher's College |
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| Abstract: | Mo-S cluster compound films on nickel surface were investigated by FT-IR,F-IR.XPS and AES. The results indicated that Mo-S-Ni,Mo -S -Mo and terminal Mo-S bonds exist in the cluster films. The films are complicated multimolecular layers of MoS2 and Mo - S-Ni cluster compounds and can be described as two overlapping layers. The mechanism for films formation of surface coordination reactions and the influence factors to form the coordination compound films are discussed. |
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| Keywords: | Metal Surface chemical reaction Coordination compound film Monolayer Multilayer |
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