| Z字形链状聚合物[ZnLCl_2]的合成和晶体结构 |
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| 引用本文： | 公维洁. Z字形链状聚合物[ZnLCl_2]的合成和晶体结构[J]. 琼州学院学报, 2012, 19(2): 8-10 |
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| 作者姓名： | 公维洁 |
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| 作者单位： | 琼州学院理工学院,海南三亚,572022 |
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| 摘 要： | 通过金属盐和1,1＇-（1,4-丁基）二咪唑（L）进行自组装得到了一个新颖的配合物[ZnLCl2],并进行了该配体的晶体结构测定。在该化合物中,每个锌离子与两个氯离子和来自L的两个氮原子配位。L桥连两个锌离子,形成Z字形链状结构。
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| 关 键 词： | 1,1＇-(1,4-丁基)二咪唑 自组装 配合物 |
Synthesis and Crystal Structure of an Zigzag Chain Coordination Polymer |
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| GONG Wei-jie. Synthesis and Crystal Structure of an Zigzag Chain Coordination Polymer[J]. Journal of Qiongzhou University, 2012, 19(2): 8-10 |
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| Authors: | GONG Wei-jie |
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| Affiliation: | GONG Wei-jie(College of Science and Engineering,Qiongzhou University,Sanya Hainan 572022,China) |
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| Abstract: | A new coordination polymer [ZnLCl2] was obatained from self-assembly of the corresponding metal salt with 1,1′-(1,4-butanediyl)bis(imidazole)(L) and its structure was determined by X-ray diffraction method.In the complex,each zinc ion is coordinated to two nitrogen atoms from two molecules of L,and to two chlorine ions.Each L molecule is coordinated to two zinc ions,acting as a bridging ligand.The bridged zinc ions form an zigzag chain structure. |
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| Keywords: | 1,1' - ( 1,4 - butanediyl) bis (imidazole) self - assembly coordination polymer |
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