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煤油络合吸附脱芳的实验研究
引用本文:崔盈贤,唐晓东,王焕梅,胡星琪,周丹. 煤油络合吸附脱芳的实验研究[J]. 西南石油大学学报(社会科学版), 2013, 30(3): 123-126. DOI: 10.3863/j.issn.1000-2634.2008.03.032
作者姓名:崔盈贤  唐晓东  王焕梅  胡星琪  周丹
作者单位:1.西南石油大学化学化工学院,四川 成都 610500; 2. “油气藏地质及开发工程”国家重点实验室·西南石油大学,四川 成都 610500;3.兰州石化职业技术学院石化系,甘肃 兰州 730060; 4.中国石油西南油气田公司天然气研究院,四川 成都 610213
摘    要:针对传统脱芳方法存在能耗高、污染环境、脱芳效果差等问题,提出了一种络合吸附脱芳新工艺,通过采用AlCl3-HCl络合剂,对高芳烃煤油进行脱芳研究。实验表明,在AlCl3浓度为0.8mol/L、HCl气体浓度为1.05mol/L、络合吸附温度60℃及吸附时间25min的操作条件下,对煤油进行络合吸附脱芳,效果明显,精制煤油芳烃含量(质量分数)降到0.68%,脱芳率达到91.1%,完全满足无芳煤油质量要求;且络合物可进一步解络,回收芳烃。

关 键 词:煤油   络合剂   吸附分离   脱芳   实验研究
收稿时间:2007-03-06

EXPERIMENTAL STUDY ON DEAROMATIZATION OF KEROSENE BY COMPLEXATION ADSORPTION
CUI Ying-xian,TANG Xiao-dong,WANG Huan-mei,HU Xing-qi,,ZHOU Dan. EXPERIMENTAL STUDY ON DEAROMATIZATION OF KEROSENE BY COMPLEXATION ADSORPTION[J]. Journal of Southwest Petroleum University(Social Sciences Edition), 2013, 30(3): 123-126. DOI: 10.3863/j.issn.1000-2634.2008.03.032
Authors:CUI Ying-xian  TANG Xiao-dong  WANG Huan-mei  HU Xing-qi    ZHOU Dan
Affiliation:1.College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu Sichuan 610500,China;2.The State Key Laboratory of Oil & Gas Reservoir Geology and Exploitation ·Southwest Petroleum University,Chengdu Sichuan 610500,China;3.Department of Petrochemical Engineering Lanzhou Petrochemical College of Technology,Lanzhou Gansu 730060,China;4.Natural gas Research Institute of Southwest Oil and gas field corporation of PetrolChina,Chengdu Sichuan 610213,China
Abstract:Considering such problems as high energy,environment pollution and low dearomatization efficiency of traditional dearomatization technology,a new complexation adsorption dearomazitation technique is proposed.Dearomazitation of kerosene is studied by using AlCl3-HCl complexant.Experimental results show that arene content in clear kerosene can be lowed to 0.68% with dearomatization efficiency of 91.1% under certain conditions,i.e.,AlCl3 dosage 0.80mol/L,HCl dosage 1.05mol/L,complexation adsorption temperature 60℃ and adsorption time 25min.The complex compound may be further decomplexed so as to reclaim the arene of raw kerosene.
Keywords:kerosene   complexant   adsorption separation   dearomatization   experimental study
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