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关于Na_2S和K_4〔Fe(CN)_6〕反应的讨论
引用本文:姚健萍. 关于Na_2S和K_4〔Fe(CN)_6〕反应的讨论[J]. 绍兴文理学院学报, 2001, 0(8)
作者姓名:姚健萍
作者单位:湖州师范学院化学系!浙江湖州313000
摘    要:Na2 S与K4 〔Fe(CN) 6〕在室温下反应不能马上产生FeS沉淀 ,其主要原因是由于〔Fe(CN) 6〕4 -水解或离解过程的晶体场活化能较高 ,因此提高反应温度或延长反应时间能够产生FeS沉淀 .

关 键 词:硫化钠  亚铁氰化钾  硫化铁  晶体场活化能

Discussion on the Reaction between Sodium Sulfide and Potassium Ferrocyanide
Yao Jianping. Discussion on the Reaction between Sodium Sulfide and Potassium Ferrocyanide[J]. Journal of Shaoxing College of Arts and Sciences, 2001, 0(8)
Authors:Yao Jianping
Abstract:The reaction between sodium sulfide and potassium ferrocyanide doesn't immediately form ferrous sulfide at room temperature,the reason is the crystal field activation energy being high in hydrolysis and decomposition of ferrocyanide. So we can produce ferrous sulfide precipitate by raising reaction temperature or postponing reaction time.
Keywords:sodium sulfide  potassium ferrocyanide  ferrous sulfide  crystal field activation energy  
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