| 一种新的吲哚乙胺型席夫碱的合成、表征及其晶体结构 |
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| 引用本文： | 刘超,卓馨,吴怡康,王丽.一种新的吲哚乙胺型席夫碱的合成、表征及其晶体结构[J].宿州学院学报,2011,26(5):60-62. |
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| 作者姓名： | 刘超 卓馨 吴怡康 王丽 |
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| 作者单位： | 宿州学院化学与生命科学学院,安徽宿州,234000 |
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| 基金项目： | 安徽省自然科学基金(090416239); 宿州学院大学生科研立项(KYLXLKYB12) |
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| 摘 要： | 以2-羟基-3-甲基苯甲醛与吲哚乙胺为原料在甲醇中反应,合成了一种新型的吲哚乙胺型席夫碱化合物;通过核磁、元素分析和X-射线单晶衍射对其结构进行了表征和确认,结果表明晶体属于六方晶系,空间群为R-3。晶胞参数：a=29.5773（9）,b=29.5773（9）,c=9.0233（6）;α=90°,β=90°,γ=120°。实验结果表明,这种方法可以合成我们所需要的物质,所得吲哚乙胺型席夫碱可能具有抗癌和杀菌等药用效果,这对以后研究合成一些新的抗癌、杀菌药物具有一定的参考价值。
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| 关 键 词： | 席夫碱 吲哚乙胺 晶体结构 合成 |
Synthesis,Characterization and Crystal Structure of a New Schiff Base of Tryptamine |
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| LIU Chao,ZHUO Xin,WU Yi-kang,WANG li.Synthesis,Characterization and Crystal Structure of a New Schiff Base of Tryptamine[J].Journal of Shuzhou College,2011,26(5):60-62. |
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| Authors: | LIU Chao ZHUO Xin WU Yi-kang WANG li |
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| Institution: | LIU Chao,ZHUO Xin,WU Yi-kang,WANG li Department of Chemistry-Biology Science,Suzhou University Anhui Suzhou,234000 |
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| Abstract: | The article synthesizes a new Schiff base of tryptamine with benzaldehyde and tryptamine in methanol;The structure of the compound is characterized and determined by NMR、elemental analysis and single-crystal X-ray analysis.The result shows that the crystal system of the crystal is hexagonal,space group is R-3.Unit cell parameters:a=29.5773(9),b=29.5773(9),c=9.0233(6);α=90°,β=90°,γ=120°.The result shows that we can get the material we need by adopting this method.The Schiff base of tryptamine may have anticancer and fungicidal officinal effect.It proves that the research is of great reference value in synthesizing some new anticancer and fungicidal medicines. |
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| Keywords: | Schiff base Tryptamine Crystal structure Synthesis |
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